全文获取类型
收费全文 | 627篇 |
免费 | 9篇 |
国内免费 | 3篇 |
专业分类
化学 | 302篇 |
晶体学 | 9篇 |
力学 | 60篇 |
数学 | 47篇 |
物理学 | 221篇 |
出版年
2021年 | 6篇 |
2020年 | 8篇 |
2019年 | 3篇 |
2018年 | 5篇 |
2016年 | 12篇 |
2015年 | 5篇 |
2014年 | 14篇 |
2013年 | 19篇 |
2012年 | 29篇 |
2011年 | 44篇 |
2010年 | 15篇 |
2009年 | 24篇 |
2008年 | 44篇 |
2007年 | 30篇 |
2006年 | 23篇 |
2005年 | 36篇 |
2004年 | 18篇 |
2003年 | 24篇 |
2002年 | 18篇 |
2001年 | 11篇 |
2000年 | 19篇 |
1999年 | 14篇 |
1998年 | 10篇 |
1997年 | 10篇 |
1996年 | 13篇 |
1995年 | 10篇 |
1994年 | 12篇 |
1993年 | 17篇 |
1992年 | 10篇 |
1991年 | 11篇 |
1990年 | 6篇 |
1989年 | 9篇 |
1988年 | 9篇 |
1987年 | 7篇 |
1986年 | 3篇 |
1985年 | 5篇 |
1984年 | 9篇 |
1983年 | 4篇 |
1982年 | 8篇 |
1981年 | 6篇 |
1980年 | 12篇 |
1978年 | 7篇 |
1977年 | 2篇 |
1976年 | 3篇 |
1974年 | 6篇 |
1973年 | 6篇 |
1971年 | 2篇 |
1922年 | 2篇 |
1906年 | 2篇 |
1882年 | 2篇 |
排序方式: 共有639条查询结果,搜索用时 765 毫秒
91.
Filippus S. Roux 《Optics Communications》2010,283(24):4855-4858
Stochastic (i.e. random and quasi-random) optical fields may contain distributions of optical vortices that are represented by non-uniform topological charge densities. Numerical simulations are used to investigate the evolution under free-space propagation of topological charge densities that are inhomogeneous along one dimension. It is shown that this evolution is described by a diffusion process that has a diffusion parameter which depends on the propagation distance. 相似文献
92.
A polarizable potential function for the hydration of alkali and halide ions is developed on the basis of the recent SWM4-DP water model [Lamoureux, G.; MacKerell, A. D., Jr.; Roux, B. J. Chem. Phys. 2003, 119, 5185]. Induced polarization is incorporated using classical Drude oscillators that are treated as auxiliary dynamical degrees of freedom. The ions are represented as polarizable Lennard-Jones centers, whose parameters are optimized to reproduce the binding energies of gas-phase monohydrates and the hydration free energies in the bulk liquid. Systematic exploration of the parameters shows that the monohydrate binding energies can be consistent with a unique hydration free energy scale if the computed hydration free energies incorporate the contribution from the air/water interfacial electrostatic potential (-540 mV for SWM4-DP). The final model, which can satisfyingly reproduce both gas and bulk-phase properties, corresponds to an absolute scale in which the intrinsic hydration free energy of the proton is -247 kcal/mol. 相似文献
93.
Green's functions can be retrieved between receivers from the correlation of ambient seismic noise or with an appropriate set of randomly distributed sources. This principle is demonstrated in small-scale geophysics using noise sources generated by human steps during a 10-min walk in the alignment of a 14-m-long accelerometer line array. The time-domain correlation of the records yields two surface wave modes extracted from the Green's function between each pair of accelerometers. A frequency-wave-number Fourier analysis yields each mode contribution and their dispersion curve. These dispersion curves are then inverted to provide the one-dimensional shear velocity of the near surface. 相似文献
94.
Giovanni DiLena Basilio Messano Delfina Roux 《Proceedings of the American Mathematical Society》1997,125(12):3575-3580
We introduce a new class of normed spaces (not necessarily finite dimensional), which contains the finite dimensional normed spaces with polyhedral norm. We study the properties of rigid sets of the spaces of this class and we apply the results to limit sets of the sequences of iterates of nonexpansive maps.
95.
Roux MV Temprado M Notario R Foces-Foces C Emel'yanenko VN Verevkin SP 《The journal of physical chemistry. A》2008,112(32):7455-7465
This paper reports the value of the standard (p(o) = 0.1 MPa) molar enthalpy of formation in the gas phase at T = 298.15 K for barbituric acid. The enthalpies of combustion and sublimation were measured by static bomb combustion calorimetry and transference (transpiration) method in a saturated N2 stream and a gas-phase enthalpy of formation value of -(534.3 +/- 1.7) kJ x mol(-1) was determined at T = 298.15 K. G3-calculated enthalpies of formation are in very good agreement with the experimental value. The behavior of the sample as a function of the temperature was studied by differential scanning calorimetry, and a new polymorph of barbituric acid at high temperature was found. In the solid state, two anhydrous forms are known displaying two out of the six hydrogen-bonding patterns observed in the alkyl/alkenyl derivatives retrieved from the Cambridge Crystallographic Database. The stability of these motifs has been analyzed by theoretical calculations. X-ray powder diffraction technique was used to establish to which polymorphic form corresponds to the commercial sample used in this study and to characterize the new form at high temperature. 相似文献
96.
The rheology of cellulose microfibril suspensions from TEMPO-oxidized pulp was investigated. The suspension showed a pseudo-plastic
and thixotropic behavior, slowly evolving with time under a given shear rate. The viscosity was proportional to the concentration
up to the critical concentration of 0.23%. Above it, the viscosity followed a power law with exponents from 2 to 6 depending
on the shear rate, and the system showed shear thinning behavior and behaved gel-like. Below this concentration, the system
was more Newtonian. Birefringence measurement of 0.44% and 0.78% suspension showed that microfibrils alignment saturated at
a small shear rate with a Herman’s orientation parameter below 0.65 probably due to the interconnection of microfibrils. 相似文献
97.
Gadolinium chelate coated gold nanoparticles as contrast agents for both X-ray computed tomography and magnetic resonance imaging 总被引:1,自引:0,他引:1
Alric C Taleb J Le Duc G Mandon C Billotey C Le Meur-Herland A Brochard T Vocanson F Janier M Perriat P Roux S Tillement O 《Journal of the American Chemical Society》2008,130(18):5908-5915
Functionalized gold nanoparticles were applied as contrast agents for both in vivo X-ray and magnetic resonance imaging. These particles were obtained by encapsulating gold cores within a multilayered organic shell which is composed of gadolinium chelates bound to each other through disulfide bonds. The contrast enhancement in MRI stems from the presence of gadolinium ions which are entrapped in the organic shell, whereas the gold core provides a strong X-ray absorption. This study revealed that these particles suited for dual modality imaging freely circulate in the blood vessels without undesirable accumulation in the lungs, spleen, and liver. 相似文献
98.
Simulating electron spin resonance spectra of nitroxide spin labels from motional models is necessary for the quantitative analysis of experimental spectra. We present a framework for modeling the spin label dynamics by using trajectories such as those from molecular dynamics (MD) simulations combined with stochastic treatment of the global protein tumbling. This is achieved in the time domain after two efficient numerical integrators are developed: One for the quantal dynamics of the spins and the other for the classical rotational diffusion. For the quantal dynamics, we propagate the relevant part of the spin density matrix in Hilbert space. For the diffusional tumbling, we work with quaternions, which enables the treatment of anisotropic diffusion in a potential expanded as a sum of spherical harmonics. Time-averaging arguments are invoked to bridge the gap between the smaller time step of the MD trajectories and the larger time steps appropriate for the rotational diffusion and/or quantal spin dynamics. 相似文献
99.
Cover Picture: Fast‐Geomimicking using Chemistry in Supercritical Water (Angew. Chem. Int. Ed. 34/2016) 下载免费PDF全文
100.
J. N. Orce M. Kumar Raju N. A. Khumalo T. S. Dinoko P. Jones R. A. Bark E. A. Lawrie S. N. T. Majola L. M. Robledo B. Rubio M. Wiedeking J. Easton E. A. Khaleel B. V. Kheswa N. Kheswa M. S. Herbert J. J. Lawrie P. L. Masiteng M. R. Nchodu J. Ndayishimye D. Negi S. P. Noncolela S. S. Ntshangase P. Papka D. G. Roux O. Shirinda P. S. Sithole S. W. Yates 《The European Physical Journal A - Hadrons and Nuclei》2016,52(6):166